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04% in January of 1928 to a high of 459% in September of 1929, the high point for five years past and two years to come With the collapse of the stock market in the autumn of 1929, pressures on the money market immediately relaxed, interest rates declined precipitately, and the bond market started to rise The prime corporate bond yield average moved from 459% in September 1929 to 399% in May of 1931 The rediscount rate by mid-1930 was down to 3%, and by mid-1931 it was down to 11 2% Call money declined from 20% to a 1931 low of 1% All this was very different from the tight money depression of 1920 1921, with its persistent 7% rediscount rate.

while some of the rings remain as hydrogenated polyquinizarine structures (XXIX). Further heating at temperatures above 2500 C in nitrogen or argon for brief periods eliminates all elements except carbon to yield carbon bers with graphitelike morphology. The carbon

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bers are subjected to a nal oxidizing atmosphere such as a mixture of gaseous nitrogen and oxygen at 350 1100 C to oxidize the surface for purposes of imparting adhesive properties The process for producing carbon bers is expensive because of the large energy expenditures required as well as the need to treat the volatile by-products (which include toxic HCN) Carbon bers combine ultrahigh strength and low density when used in composite formulations with epoxy and other resins More than 50% of carbon ber use is in air and spacecraft applications where weight and fuel savings are achieved without sacri cing performance A variety of components of air and spacecraft are fabricated from carbon ber epoxy composites Carbon ber epoxy composites have been used to produce the entire aircraft structure of a business jet (Lear 2100) and the payload bay doors of a space shuttle.

The Federal Reserve System was leaning against a very big wind indeed, or so it seemed if one ignored the collapse of the money stock and the price level In 1931 the Treasury resumed its long-term financing, after a lapse of three years, and took full advantage of the lower interest rates then prevailing: $06 billion 33 8s of 1941 1943, PTE, sold at 100 = 337% 1931, June 08 billion 31 8s of 1946 1949, PTE, sold at 100 = 312% 1931, September 08 billion 3s of 1951 1955, PTE, sold at 100 = 300% The last issue was unfortunately timed on the eve of a crisis Allotments ranged up to 100%, the first quotations were at 995 8, and within four months the bonds sold down to 821 8, to yield 424%.

Carbon bers combined with higher-performance matrix materials such as polyimides or polybenzimidazole offer the potential for further improvements Civilian applications include sporting goods golf-club shafts, tennis racquets, shing rods, and boat masts The lighter weight of the carbon ber composite (compared to the metal component it replaces) allows a redesign of the item for improved performance The lighter golf-club shaft allows a heavier head design Other applications include high-quality loudspeakers and various medical applications, including arti cial limbs and surgical implants Other polymers undergo cyclization, but there are no commercial applications Poly (methacrylic acid) cyclizes by anhydride formation and poly(methyl vinyl ketone) by condensation (with dehydration) between methyl and carbonyl groups 9-8 OTHER REACTIONS Hydrogenation of double bonds is practiced with some elastomers such as SBR and NBR to increase high temperature and oxidative resistance [Hsieh, 1998; Hsieh and Quirk, 1996, Wrana et al, 2001].

You ve gathered all the needed parts and you ve opened things up. You ve studied the diagram. Now, step by step, you ll complete the transformation. Here s how.

Only partial hydrogenation is performed since some double bonds are required to achieve the subsequent crosslinking required to achieve elastic behavior Epoxidation of double bonds in poly(1,3-dienes) yield epoxy resins that are subsequently crosslinked (Sec 2-12d) 9-9 GRAFT COPOLYMERS Graft and block copolymers contain long sequences of each of two different monomers in the copolymer chain A block copolymer contains the sequences of the two monomers in a continuous arrangement along the copolymer chain while a graft copolymer contains a long sequence of one monomer (often referred to as the backbone polymer) with one or more branches (grafts) of long sequences of a second monomer (Secs 2-13a, 6-1b) A variety of techniques for synthesizing such structures have been studied.

Most methods of synthesizing graft copolymers involve radical polymerization, but ionic graft polymerizations are also possible [Battaerd and Tregear, 1967; Ceresa, 1973, 1976; Dreyfuss and Quirk, 1986; Gnanou, 1996; Gnanou and Taton, 2002; Rempp and Lutz, 1989] Graft polymerizations are carried out in heterogeneous as well as homogeneous systems Three methods exist for synthesizing graft copolymers Grafting onto involves the reaction between functional groups on two different polymers:.

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