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moderately. The Federal Reserve Banks maintained their 7% crisis rate unchanged until the sweeping deflation of 1920 1921 was about completed. In this one year, Reserve Bank credit declined from $3.5 billion to $1.5 billion, commodity prices declined almost 50%, and industrial production declined one-third. At last, after the spring of 1921, the rediscount rate was reduced in a series of steps from 7 to 4%. The crisis was over. Business, although still depressed, improved. A really important decline in corporate bond yields began in June of 1921. In fifteen months, yields moved from close to the highs to close to the lows of the 1920s. The average yield of long-term P.T.E. governments declined from its 1921 high of 5.27% to a 1922 low of 4.12%. Fourth Liberty 41 4s of 1933 1938 were up from 82 in 1920 to 1013 4 in 1922. The entire postwar decline in the bond market was erased in about a year. The Treasury enjoyed a surplus, and the war debt was reduced. Treasury long-term financing during the 1920s was confined to refunding issues at almost steadily declining yields as shown below.

FIGURE 31-2: Bending diagram for the Casio DH 100. Experiment with other potentiometer values for different effects.

9-7 CYCLIZATION Natural rubber and other 1,4-poly-1,3-dienes are cyclized by treatment with strong protonic acids or Lewis acids [Golub, 1969; Subramaniam, 1988]. The reaction involves protonation of the double bond (Eq. 9-40) followed by cyclization via attack of the carbocation on the double bond of an adjacent monomer unit (Eq. 9-41). Some bicyclic and polycyclic

9-40

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From 1922 on, this decade was characterized by rising prosperity except in the field of agriculture Commodity prices declined The total of private debt approximately doubled Nevertheless, American savings not only financed this credit expansion but also permitted the purchase of some $45 billion of foreign long-term securities and after 1925 financed stock market speculation Throughout the boom years after 1922, bond yields fluctuated in a moderate range Short-term rates became far lower than they had ever been during pre-World War I periods of prosperity In early 1928, however, there began a brief period of rising interest rates, which lasted until the fateful autumn of 1929 Between January of 1928 and August of 1929, the rediscount rate was raised four times, moving from 31 2 to 6% Call money rose from 31 2 to 20% Prime corporate bond yields rose moderately, from 4.

9-41

fused-ring structures are formed by propagation of the cyclization reaction through more than two successive monomer units. However, the average number of fused rings in a sequence is only 2 4 because of the steric restrictions involved in the polymer reaction as well as competing transfer reactions and the isolation of unreacted monomer units between pairs of cyclized units. Cyclized rubbers have been used for shoe soles and heels, adhesives, hard moldings, and coatings. Cyclization is a key reaction in the production of carbon bers from polyacrylonitrile (PAN) (acrylic ber; see Sec. 3-14d-2). The acrylic ber used for this purpose usually contains no more than 0.5 5% comonomer (usually methyl acrylate or methacrylate or methacrylic acid). Highly drawn (oriented) bers are subjected to successive thermal treatments initially 200 300 C in air followed by 1200 2000 C in nitrogen [Riggs, 1985]. PAN undergoes cyclization via polymerization through the nitrile groups to form a ladder structure (XXVII). Further reaction results in aromatization to the polyquinizarine structure (XXVIII)

Notice the miniature SMD resistors (black, two lead), capacitors (terra cotta brown), transistors (black, three lead), and others such tiny components on the board. Each has an identifying title associated with it. Resistors are marked nearby R1, R2, and so on; capacitors are C1, C2, and so on; and transistors are coded T1, T2, and so on. Look closely at an SMD resistor or capacitor. The shape is that of a tiny rectangular box, each end terminated by a minuscule metal cap. Hold your breath and turn on your internal gyroscopes: It is to these silvery caps you ll be soldering. The diagram shows SMDs as white blocks, but the wiring indicates to which side of the SMD (silver cap) you ll solder to.

9-42

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